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| material safety data sheet tt-p - 1757b ty. i cl. c yellow zinc chromate primer 1. product and company information manufacturer information 24 hr. emergency telephone number intrepid coatings chemtrec (us tra n sportation) : 1 (800)424 - 9300 1910 east riverview drive chemtrec (international transportation) : +1(202)483 - 7616 phoenix, az 85034 phone: (602)243 - 3293 fax: (602)268 - 6801 contact : robert d. commisso 2. hazards identification emergency overview physical appearance : liquid imme diate concerns : danger! flammable liquid and vapor. may cause eye, skin and respiratory tract irritation. may cause asphyxiation, or brain, lung or other organ injury if inhaled, swallowed or absorbed by the skin. potential health effects eyes : liquid is severely irritating to the eyes. high vapor concentrations are also irritating. skin : liquid is moderately irritating to the skin. prolonged or repeated contact can result in drying of the skin which may result in skin irritation and dermatitis (rash). liquid may be absorbed through the skin. ingestion : ingestion may cause headache, dizziness, fatigue, and central nervous system depression along with gastrointestinal disturbances. inhalation : vapors may be irritating to the nose, throat, and respirat ory tract. exposure to high vapor concentrations may cause central nervous system (cns) depression. aspiration of liquid may cause pneumontitis, pulmonary edema, and hemorrhaging. chronic : no chronic health concerns known. carcinogenicity : this material is not currently known to have carcinogenic properties. mutagenicity : this material is not know to have mutagenic effects on genetic material. i rritancy: this material may cause irritation to the eyes, skin, and respiratory tract. use correct ppe when handling this material. date issued : 11/18/2013 msds ref. no : 111313 product name: tt - p - 1757b ty. i cl. c yellow zinc chromate primer product code: 111313 page 1 of 11 free datasheet http://
111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer reproductive tox ici ity reproductive effects : this material is not known to cause any reproductive system damage. teratogenic effects : this material is not known to contain any teratogenic substances. 3. composition/ chemical in formation chemical name cas number weight % *zinc potassium chromate 13530 - 65 - 9 20% to 25% *xylenes, mixed isomers 1330 - 20 - 7 15% to 20% phenolic resin solids proprietary 15% to 20% limestone 1317 - 65 - 3 5% to 10% *acetone 67 - 64 - 1 5% to 10% 2 - propanone 67 - 64 - 1 5% to 10% talc 14807 - 96 - 6 5% to 10% titanium dioxide 13463 - 67 - 7 1% to 5% barium sulfate 7727 - 43 - 7 1% to 5% * toxic chemical subject to the reporting requirements of section 313 of title iii and of 40 cfr 372. 4. first aid measures eyes : immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. seek medical aid if irritation persists. skin : flush skin with soap and water while removing contaminated clothing. if irritation occurs, se ek immediate medical attention. do not reuse clothing or shoes until thoroughly cleaned. ingestion : do not induce vomiting, and seek immediate medical attention. do not attempt to give any liquids if victim is unconscious. inhalation : immediately remo ve victim to fresh air. if victim is not breathing, give artificial respiration. if breathing is difficult, oxygen should be administered by qualified personnel. seek immediate medical attention. notes to physician: if the victim is a child, give no more than 1 glass of water and 15cc (1 tablespoon) syrup of ipecac. if symptoms such as loss of gag reflex, convulsions, or unconsciousness occur before emesis, gastric lavage should be considered following intubation with a cuffed endotracheal tube. page 2 of 11 free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer 5. fire f ighting measures flash point and method : 56 degrees fahrenheit tagliabue closed cup (tcc) flammable limit s : 0.0% to 12.8% autoignition temperature : no data available. general hazard : carbon monoxide and unidentified organic compounds may be formed during combustion. extinguishing media : use water fog, "alcohol" foam, dry chemical, or co2. fire fighting procedures : warning! flammable liquid. clear the fire area of unprotected personnel. do not enter confined fire space without full bunker gear; including a positive pressure niosh approved scba. cool fire exposed containers with water. if water is used, fog nozzles are preferred explosion hazard : when heated above the flash point, this material emits flammable vapors which, when mixed with air, can burn or be explosive. fine mists or sprays may be flammable at temperatures below the flash point. 6. accidental release measures general procedures : warning. flammable. ventilate area of leak or spill for at least 24 hours or until it has been dec lared safe. remove all sources of ignition. stop the leak if there is no risk involved. clean - up personnel require protective clothing and respiratory protection from vapors. absorb liquid with inert material. only specially trained or qualified personnel should handle the emergency. environmental precautions water spill : keep material out of storm sewers and ditches which lead to waterways. land spill : contact applicable authorities and determine applicable regulations based on msds information. air release : contact applicable authorities and determine applicable regulations based on msds information. 7. handling and storage general procedures : keep away from heat, sparks, and flame. surfaces that are hot may ignite liquid even in the absence of sparks or flame. extinguish pilot lights, cigarettes, and turn off all other sources of ignition prior to use, and until all vapors are gone. keep containers tightly closed and upright to prevent leakage. comments : keep out of reach of children! emp ty containers retain product residue and can be dangerous. do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition. 8. exposure controls/ personal protectio n page 3 of 11 free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer exposure guidelines : osha hazardous components (29 cfr 1910.1200) exposure limits chemical name osha pel acgih tlv ppm mg/m 3 ppm mg/m 3 *zinc potassium chromate twa n/a 0.005 n/a 0.001 stel n/a nl n/a nl *xylenes, mixed isomers twa 100 435 100 435 stel nl nl 150 635 limestone twa n/a 15 n/a 10 stel n/a nl n/a nl *acetone twa 1000 2400 250 590 stel nl nl nl nl 2 - propanone twa 1000 2400 250 590 stel nl nl nl nl talc twa n/a 20 mppcf n/a 2 stel n/a nl n/a nl titanium dioxide twa n/a 15 n/a nl stel n/a nl n/a nl barium sulfate twa n/a 15 n/a 10 stel n/a nl n/a nl osha table comments: nl = not listed ca = "warning: this product contains chemicals known to the state of california to cause cancer and birth defects or other reproductive harm." engineering controls: provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits. exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination . personal protective equipment eyes and face: use chemical safety goggles and/or full face shield where splashing is possible. contact lenses should not be worn when working with this material. maintain eye wash fountain and quick - drench facilities in w ork areas. skin: wear resistant gloves (consult your safety equipment supplier). to prevent repeated or prolonged skin contact, wear impervious clothing and boots. respiratory: if exposure may or does exceed occupational exposure limits (section 8) use a niosh approved respirator to prevent overexposure. in accord with 29 cfr 1910.134, use either an atmosphere - suppling respirator or an air - purifying respirator for organic vapors. hygienic work practices: use good personal hygiene when handling this product. wash hands after use, before eating, drinking, smoking, or using the toilet. other use precautions: facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. page 4 of 11 free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer comments: may be harmful or fatal if swallowed. may irritate body tissues. use with adequate ventilation. avoid breathing vapor. do not get in eyes, on skin, on clothing. wash thoroughly after handling. 9. physical and chemical properties physical state : liquid odor : typical paint odor. ph : not applicable boiling point : 133 degrees fahrenheit to 244 degrees fahrenheit freezing point : no data available volatile or ganic compounds : 354 g/l (2.95 lbs/gal) (voc theoretical ? as packaged) hazardous air pollutants (hap?s): 305 g/l (2.54 lbs/gal) (hap?s theoretical ? as packaged) solubility in water : soluble in most organic solvents. not soluble in water. evaporation rate : no data available density : 11.12 (lbs/gal) 10. stability and reactivity stable : yes hazardous polymerization : will not occur conditions to avoid : avoid heat, sparks, flame and contact with strong oxidizing agents. prevent vapor accumulation. polymerization : avoid heat, flame, and other sources of ignition. hazardous decomposition pr oducts: carbon monoxide and unidentified organic compounds may be formed during combustion. incompatible materials : strong oxidizers. 11. toxicological information general comments: none identified. 12. ecological information ecotoxicological informa tion: keep out of waterways. 13. disposal information disposal method: this material is a us epa defined ignitable hazardous waste. the preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. any disposal practice must be in compliance with federal, state, and local regulations. do not dump into sewers, ground, or any body of water. page 5 of 11 free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer empty container: keep out of reach of children! empty containers retain product residue and can be dangerous. do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition. rcra/epa waste information: chemical waste generators must determine whether a discarded chemical is classified as a haza rdous waste. us epa guidelines for the classification determination are listed in 40 cfr. additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 14. transport information d ot (department of transportation) proper shipping name : un1950, aerosols, class 2.1 (consumer commodity, orm - d for ground transportation) (un#, proper shipping name, class, packing group) *** intrepid coatings verifies that the material was supplied and shipped in the proper packages in accordance with dot and federal regulations that are applicable to the mode of transportation selected. the shipper must verify that the packaging supplied is acceptab le to be re - shipped in per the federal regulations applicable to the mode of transportation for re - shi pment. regulations may change depending on mode of transportation selected.*** sara title ii i (superfund amendment s and reauthorization act) 311/312 hazard categories : this product should be reported as an immediate (acute) health hazard, delayed (chronic) health hazard, and a fire hazard. fire : yes pressure generating : no reactivity : no acute : yes chronic : yes 313 reportable ingredients: to the best of our knowledge, this product is not listed as a toxic chemical. 302/304 emergency planning emergency plan: to the best of our knowledge, this material is not listed as an extremely hazardous substance. 16. other information approved by : robert d. commisso title : president / qc manager hmis rating health : 3 flammability : 4 reactivity : 0 personal protection : h manufacturer disclaimer : to the best of intrepid coatings, inc.'s knowledge, all information, recommendations, and suggestions appearing herein concerning this product are taken from raw material sources or based upon data believed to be reliable. although reasonable 15. regulatory information 4 0 3 nfpa codes page 6 of 11 free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer care has bee n taken in the preparation of this information, intrepid coatings, inc. extends no guarantees, express or implied, makes no representations and assumes no responsibility as to the accuracy, reliability or completeness of the information presented. intrepi d coatings, inc. assumes no liability arising out of the use of the product by others. the conditions or methods of handling, storage, use and disposal of the product are beyond intrepid coatings, inc.'s control. the information provided herein may not be valid for this product if it is used in combination with any other materials or process. it is the user's responsibility to determine the suitability of the product, review the information provided herein, assess the safety and toxicity of the product and to comply with all applicable laws and regulations. for this and other reasons, intrepid coatings, inc. does not assume responsibility and expressly disclaims liability for any loss damage or expense arising out of or in any way connected with the han dling, storage, use or disposal of the product. free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer material safety data sheet unfilled omni - pak ? cans used with omni - fill ? package omnifill/ isd enamel blend lacquer, acrylic, vinyl ---- section ii ---- cas no. hazardous ingredient (percent by weight) acgih osha vapor tlv pel units pressure 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer unfilled omni - pak ? cans used with omni - fill ? package omnifill/ isd section iii ? physical data product weight - n.a. evaporation rate - faster than ether specific gravity - n.a. vapor density - heavier than air boiling range - <0 - 342 of melting point - n.a. volatile volume - 100 % solubility in water - n.a. section iv ? fire and explosion hazard data flammability classification flash point <0 f pmcc lel 1.0 uel 12.8 red label C extremely flammable, flash below 21 of extinguishing media carbon dioxide, dry chemical, foam unusual fire and explosion hazards closed containers may explode (due to the build- up of pressure) when exposed to extreme heat. specia l fire fighting procedures full protective equipment including self - contained breathing apparatus should be used. water spray may be ineffective. if water is used, fog nozzles are preferable. water may be used to cool closed containers to prevent pr essure build - up and possible autoignition or explosion when exposed to extreme heat. section v ? health hazard data routes of exposure exposure may be by inhalation and/or skin or eye contact, depending on conditions of use. to minimize exposure, section vii ? spill or leak procedures steps to be taken in case material is released or spilled remove all sources of ignition. ventilate and remove with inert absorbent. waste disposal method waste from this product may be hazardous as defined under the resource conservation and recovery act (rcra) 40 cfr 261. waste must be tested for ig nitability to determine the applicable epa hazardous waste numbers. do not incinerate. depressurize container. dispose of in accordance with federal, state, and local regulations regarding pollution. section viii ? protection information precautions to be taken in use use only with adequate ventilation. avoid breathing vapor and spray mist. avoid contact with skin and eyes. wash hands after using ventilation local exhaust preferable. general exhaust acceptable if the exposure to materials in section ii is maintained below applicable exposure limits. refer to osha standards 1910.94, 1910.107, 1910.108. respiratory protection if personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by niosh/msha for protection against materials in section ii. protective gloves wear gloves which are recommended by glove supplier for protection against materials in section ii. eye protection wear safety spectacles with unperforated sideshields. free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer follow recommendations for proper use, ventilation, and personal protective equipment. acute health hazards effects of overexposure ir ritation of eyes, skin and respiratory system. may cause nervous system depression. extreme overexposure may result in unconsciousness and possibly death. signs and symptoms of overexposure headache, dizziness, nausea, and loss of coordination are in dications of excessive exposure to vapors or spray niate. redness and itching or burning sensation may indicate eye or excessive skin exposure. medical conditions aggravated by exposure none generally recognized. emergency and first aid procedure s if inhaled: if affected, remove from exposure. restore breathing. keep warm and quiet. if on skin: wash affected area thoroughly with soap and water. remove contaminated clothing and launder before re - use. if in eyes: flush eyes with large amounts of water for 15 minutes. get medical attention. if swallowed: never give anything by mouth to an unconscious person. do not induce vomiting. give several glasses of water. seek medical attention. chronic health hazards no ingredient in this product is an iarc, ntp or osha listed carcinogen. prolonged overexposure to solvent ingredients in section ii may cause adverse e ffects to the liver and urinary systems. reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. section iv ? reactivity data section ix ? precautions dol storage category - 1a precautions to be taken in handling and storing contents are extremely flammable. keep away from heat, sparks, and open flame. vapors will accumulate readily and may ignite explosively. during use and until all vapors are gone: keep area ventilated C do not smoke C extinguish all flames, pi lot lights, and heaters C turn off stoves, electric tools and appliances, and any other sources of ignition. consult nfpa code. use approved bonding and grounding procedures. contents under pressure. do not puncture, incinerate, or expose to te mperature above 120 of. heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. do not take internally. keep out of th e reach of children. other precautions intentional misuse by deliberately concent rating and inhaling the contents can be harmful or fatal. this material safety data sheet conforms to the hazard communication standard, 29 cfr 1910.1200(g)(4), for similar complex mixtures. the above information pertains to this product as currently formulated, and is based on the information available at this time. addition of reducers or other additives to this product may substantially alter the composition and hazards of the product . since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. free datasheet http:// 111313 tt - p - 1757b ty. i cl. c yellow zinc chromate primer stability - stable incompatibility none known hazardous decomposition products by fire: carbon dioxide, carbon monoxide hazardous polymerization - will not occur free datasheet http:// |
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